Answer: The pair which shares the same empirical formula is [tex]NO_2\text{ and }N_2O_4[/tex].
Explanation: Empirical formula is defined as the chemical formula in which the elements in the compound are present in simplest ratio.
So, from the given pairs, only [tex]NO_2\text{ and }N_2O_4[/tex] shares the same empirical formula which is [tex]NO_2[/tex]